N nixon13 Full Member 10+ Year Member 15+ Year Member Jul 19, 2008 #1 Advertisement - Members don't see this ad Does free radical halogenation with Br2 and Cl2 follow Markovnikovs or anti-Mark?
Advertisement - Members don't see this ad Does free radical halogenation with Br2 and Cl2 follow Markovnikovs or anti-Mark?
A atlanta213 Full Member 10+ Year Member 15+ Year Member Jul 19, 2008 #2 In free radical condition, br add to most substituted and cl add to less substituted. Upvote 0 Downvote
Xtian Full Member 10+ Year Member 15+ Year Member Jul 19, 2008 #3 because Br is a very slow addition, so goes for most stabilized by substitution, and Cl is very fast, so goes for most accessible. Upvote 0 Downvote
because Br is a very slow addition, so goes for most stabilized by substitution, and Cl is very fast, so goes for most accessible.