This problem is from Achiever 2, ok, there's a problem similar to this in Topscore 2, # 68 & another one at the end of the acids & bases chap, the review questions section. The way a girl & I came up with this at kaplan was that first, you're neutralizing the acid & the base, so you would use the titration formula: N1V1 = N2V2, then you're diluting the acid-base solution with more acid, hence the pH = 2. I'm still working on visualizing this problem so it becomes second nature to me. As you can see from the solution, the titration formula has to be used twice, & in the second titration formula, you're adding more volume, so the variable you're solving for is taking that into account. This is kind of hard to explain, I hope that helps, if not let me know, & we'll try it from another angle. Happy studying!