Ochem: alyknes/halogens

Started by 123321
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123321

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general question,

do all halogens reduce a alkyne trans?
 
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If you're talking about the common dihalides (Br2, Cl2) , they will usually reduce an alkyne to the trans alkene via anti addition (remember we form a cyclic halonium ion intermediate, and we always attack that from the opposite side).

Of course if you had add two equivalents/excess dihalide it doesn't matter, since it will be an alkane at that point.
 
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