I haven't done MCAT test-question analysis or anything, but I took a Princeton Review MCAT class, and I think the main things I learned were the values for major functional groups (carbonyls and hydroxyl groups mainly) for IR-spec and maybe H-NMR. I also learned about extractions and the concepts behind those.
Off the top of my head, those seemed to be the major things we learned, but I can't quite remember if I encountered them on the test. If I did, there weren't many questions on lab techniques on the test, if any at all.