Simple question on water's autoionization

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zut212

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A glass of pure water sits at room temperature. Which of the following is true:
A. There is about one hydrated H+ for every one billion water molecules in the glass.
D. The total number of hydrated H+ and OH- ions exceeds the total number of water molecules.












ANS: D. Their explanation is - "the equilibrium for the autoionization lies far to the left." . IMHO, the total number of H+ and OH- is MUCH MUCH less than that of the H2O, and so I think that this is an error.
 
A glass of pure water sits at room temperature. Which of the following is true:
A. There is about one hydrated H+ for every one billion water molecules in the glass.
D. The total number of hydrated H+ and OH- ions exceeds the total number of water molecules.

ANS: D. Their explanation is - "the equilibrium for the autoionization lies far to the left." . IMHO, the total number of H+ and OH- is MUCH MUCH less than that of the H2O, and so I think that this is an error.

That must be an error. The ionization of water is extremely low (Kw = 1x10^-14). That in itself would tell you that there's much more water than either hydronium or hydroxide ions combined. Where'd this question come from?
 
this question comes from Exam Kracker's 1001 questions for chemistry, and it's question 772.

I knew that I was right. Thanks.
 
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