A single crossover is when homologous chromosomes are aligned and chromatids from two different chromosomes can exchange segments resulting in genetic recombination.
In double crossovers, chromatids from two homologous chromosomes come in contact at two points.
Another comparison is shown here
THIS is a great link that will teach you how to determine linkage distance using some simple crosses (likely to show up on the MCAT)
Hoep this helps, good luck!