When I started my post-bac, all I could think about was the C- I got in Gen Chem II (my final science before giving up premed altogether as an undergrad), so my confidence was super low.
For my first semester as a post-bac, I worked full-time and took biology and gen chem I, each with lab, and it worked out really well. Here's what I did to gain confidence:
1. Go to all the classes.
2. Take good notes; be nerdy and have different-colored pens/pencils around so as to distinguish cellular components, formulas, problems, and whatnot.
3. Do the assigned reading.
4. Do the assigned problems (if applicable); and mark the ones you missed in yellow highlighter pen. Return to those as you continue to learn the material for the upcoming test. This will reinforce the material you had trouble grasping.
5. Go over notes every so often; learning happens in layers for me, so it helped to see the material consistently over a period of time rather than cramming.
The more you look at something, the easier it becomes. You can do it!
Good luck!