TBR: deltaG and K Relationship

This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.

justadream

Full Member
10+ Year Member
Joined
Apr 29, 2011
Messages
2,171
Reaction score
863
TBR GC Book II page 137 Example 8.3



“A reaction that is spontaneous in the forward direction corresponds with which of the following features??



Correct: It has a ratio of Q(of reaction) to Keq that is less than 1.



Incorrect: It has an equilibrium constant that is greater than 1.0.

I get that some reactions with a Keq < 1 are spontaneous (I think water dissociating into H and OH would be an example).



But I’m confused when I try to apply it to an equation. For example, what if you are at standard conditions where deltaG° = -RTln(Keq). In this scenario, doesn’t K have to be greater than 1 in order for deltaG° to be negative?



If someone could explain clearly when to use deltaG° and when to use deltaG?
 
Top