TBR GCHEM book2 page 294

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pizza1994

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My question is from TBR gchem passage XII question 81 regarding metal purification!

Why is the book calculating their "E rxn" values kind of weird....

Ist E of the rxn= RED - OX

so for AgCl I would write 0.56 V
CuBr2 I would say 0.75
NiBr2 is 1.32
ZnCl2 is 2.12

I know the answer is the same in terms of least applied voltage..but why is their explanation different?
 
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