I read it backwards. I make that mistake too often. It is testing the theory of compressibility factor of gasses The volume calculated using the ideal gas law would be higher than the measured volume at 200 atm.
PV/RT will always equal 1 for an ideal gas, so you can draw a line at y=1 to represent an ideal gas.
Then you can quickly see that V is the only variable item in the ratio so the measured V is low at 200 atm, and high at 600 atm. Thats the way you should look at it.
The first way I looked at it, which is kind of a time trap was to analyze the slope of the curve fir CH4 between 200 atm, and 600 atm, and found that a 3x change in P corresponded to a V.fnl of 2V.i/3. And for the ideal gas we know a 3x increase in P will give 0.33V.i. The ratio of calculated to measured at 200 atm was about 1:0.7 and the ratio at 600 atm was about 0.33:0.45