the probability can't be 10.
probability has to be on the interval [0, 1].
10 tells you how many different ways you could throw the die 5 times and get 4 twice.
here's how i would do it:
P(X=2) = (5 choose 2) * (1/6)^2 * (5/6)^3, where X=2 "successes"
P(X=2) = 10 * 1/36 * 125/216
P(X=2) = 0.16075
...which I believe is equivalent to that solution that the OP posted.
remember... 5 choose 2... because you are throwing it 5 times and are "choosing" 4 twice. 1/6 to the second because there is a 1 in 6 chance of rolling a 4, and you have to do it exactly twice. 5/6 to the third, because there is a 5 in 6 chance of NOT rolling a 4, and you have to do it exactly 3 times.
hope this helps!