BR Chemistry Chapter 3 passage 8 please help

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2010premed

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If anyone has the book, this passage really confuses me. I have the hardest time with passages about solubility for some reason. I mainly don't understand what column 3 (experiment 1) is showing... I understand that column 4 (exp 2) has the volume of where to get the molar solubility from. Also, what's the different of when they ask for the greatest molarity or the greatest molarity of a saturated solution? How do you know which column to use for the former? B/c I don't understand a lot of the passage, I'm having troubles with questions 51, 54, 55, and 56

Help is greatly appreciated.

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