How do actual volume and predicted volume of a gas compare at:
1)moderately high pressure?
At moderately high pressure, gas particles get closer to one another. Thus, the Van der Waals force between them becomes stronger. As a result, the volume would be smaller than what's predicted under standard conditions.
2)Extremely high pressure?
At extremely high pressure, gas particles get way too close. Thus, the volume of each particle becomes significant compared to the distance between particles (Recall that for ideal gasses you can essentially ignore the volume of each particle compared to the distance between them). When the volume of each particle become significant, you can no longer ignore it. As a result, the total volume will be greater than what's predicted under standard conditions.
3)very low temp?
At low temperature, the kinetic energy of gas particles drops significantly (gas particle won't move as fast). Subsequently, they can interact with one another more effectively, which will in turn result in stronger Van der Waals forces (similar to case#1). As a result, the particles are drawn close to one another, which will in turn cause the true volume of the gas to be smaller than what's predicted under standard conditions.
Answer:
1) less than predicted
2) more than predicted
3) less than predicted
Can someone explain each scenario? Thanks