Specific heat question from Chad's video

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bretonnia

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In one of the quizzes in Chad's calorimetry lecture, he asks:
After a 50g piece of an unknown metal at 50°C is added to 50g of H2O(l) at 0°C, the mixture reaches thermal equilibrium at 10°C. What is the specific heat of the metal? (specific heat of water is 1cal/g×°C)

In the solution, he begins by stating the equation: q(water) + q(metal) = 0

I can do the rest, but I don't understand why he set q(water) + q(metal) equal to zero. Is it because the water and metal are at thermal equilibrium?

Thanks in advance.
 
It's because the heat released by the metal is equal to the heat gained by the water.

Thus, -qmetal = qwater (same thing as qmetal = -qwater)
and why qwater + qmetal = 0

Another way to view it is this is a closed environment, so the heat released by the system (metal) is gained by the surroundings (water) and therefore, the net effect is equal to 0.
 
One way I look at this question is that q=MC(delta)T.

So you know its a contained system. Thus, q=MC(delta)T of Water must equal q=MC(delta)T of the Metal. So just set up the equation like MC(delta)T=MC(delta)T, plug in the given for the metal on one side and the given for water on the otherside (sidenote: The Otherside is a great RHCP song!), then plug and chug baby.
 
To set up this equation, would it be the following:

Delta H = (50 g unknown metal)(1)(50-10 degrees Celsius)

Correct?
 
One way I look at this question is that q=MC(delta)T.

So you know its a contained system. Thus, q=MC(delta)T of Water must equal q=MC(delta)T of the Metal. So just set up the equation like MC(delta)T=MC(delta)T, plug in the given for the metal on one side and the given for water on the otherside (sidenote: The Otherside is a great RHCP song!), then plug and chug baby.

This is wrong. I initially did it like this and ended up with -0.25, which is incorrect. The first few posts are correct in stating that you have to have them sum to 0 in order to have your signs straight; and this is due to the heat loss of one system being absorbed by the other.
 
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