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Item 112: Which of the following experimental modifications will most likely improve the degree of separation between limonene and carvone?
A. heating distillation flask at slower rate
B. Using a vacuum source that can achieve a lower pressure inside the distillation apparatus
I don't understand why having a lower pressure inside the apparatus would "narrow their difference in boiling temperature". Even so, narrowing this difference doesn't tell you the whole story I feel.
I was thinking along the lines of the maxwell Boltzmann distribution. If both T_boils are lowered, we lower solution temperature to the temp of the one with the lowest BP. Now both temperature distributions become much narrower because of the lowered solution temp and thus you have less "tail" extending out into the region of sufficient energy for boiling for the product we don't want to boil. I thought a broad distribution for both compounds in solution (in order to reach a high T_boil) would be bad news bears for separation compared to a lower temp, even if the t_boil for each was slightly closer.
Can anyone help me eliminate B or give me a better intuition for why A is right?
A. heating distillation flask at slower rate
B. Using a vacuum source that can achieve a lower pressure inside the distillation apparatus
I don't understand why having a lower pressure inside the apparatus would "narrow their difference in boiling temperature". Even so, narrowing this difference doesn't tell you the whole story I feel.
I was thinking along the lines of the maxwell Boltzmann distribution. If both T_boils are lowered, we lower solution temperature to the temp of the one with the lowest BP. Now both temperature distributions become much narrower because of the lowered solution temp and thus you have less "tail" extending out into the region of sufficient energy for boiling for the product we don't want to boil. I thought a broad distribution for both compounds in solution (in order to reach a high T_boil) would be bad news bears for separation compared to a lower temp, even if the t_boil for each was slightly closer.
Can anyone help me eliminate B or give me a better intuition for why A is right?