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How do you figure out which compound has the highest molar solubility when given a list of compounds and their associated Ksps?
I wanna say the higher the Ksp the the higher the solubility bc it means that the rxn favors the dissociated products... if thats what your asking?
Yes and no - How does the number of dissociated ions play into this - b/c the answer that I have for the particular problem I am referring to actually has the lowest KSP but the greatest number of moles of dissociated ions. - Is that basically how you figure it out - the number of moles of dissociated ions times the ksp and the highest number is the highest molar solubility?
whats the question anyway im curious?
Which of the following has the highest molar solubility?
BaCrO4 (Ksp = 2.1 x 10^-10)
AgCl (Ksp = 1.6 x 10^-10)
Al(OH)3 (Ksp = 3.7 x 10^-15)
PbCO3 (Ksp = 3.3 x 10^-14)
I'll provide the answer that I have if you indicate how you would figure this out and which one you would pick.
Okay molar solubility is the solubility of the compound in mol/L.
So solve for x:
I'm kinda lazy but if I had to guess you said the answer was the one w the smallest Ksp so ill do it for Al(OH)3.
Al(OH)3 -> Al3+ + 3OH-
Set up the equation:
Ksp = [Al][OH]^3
(solids arent included so thats why theres no denom. w AlOH3)
Now:
Ksp = [x][3x]^3 = 27x^4
3.7e-15 = 27x^4
Solve for x which is equal to the molar solubility. Repeat for all. Whichever one is the highest has the highest molar solubility.
BaCrO4 since its Ksp is the highest?
lol im trying to find a calculator but cant .. but what if you now took that number since x is mol/L and multiply it by the # of dissociated ions .. so Al(OH)3 ud do 9e-6 * 4 .. and then after that is Aloh3 the highest?
I think your instructor might just be confused
Ksp is not always a good indicator of a salts relative solubility b/c the units of solubility vary with the # ions.