Orgo Sterochemistry

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nixon13

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On fischer projections, can someone explain to me the trades that you can make between the substituents to determine enantiomers, diastereomers etc...
 
On fischer projections, can someone explain to me the trades that you can make between the substituents to determine enantiomers, diastereomers etc...

S-R -> R-R = diast.
S-R -> S-S = diast.
S-R -> R-S = enant.
R-S -> S-R= enant.
 
I just remember that if you have an inversion of configuration at every chiral center it is an enantiomer. If atleast one of them stays the same it will be a diastereomer.
 
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