Why does an increase in activation energy (Ea) cause a decrease in the rate constant (k)?

Started by Merisa15
This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.
Get help with your application

Use all the free resources available to you from SDN: articles, guides, expert advising, forums discussions, and school research.

Merisa15

Full Member
5+ Year Member
2+ Year Member
Advertisement - Members don't see this ad
Just watched Chad's video where he explains that high activation energy equates to a low rate constant. I don't understand why. Can someone explain?

Thank you.


Soooooo, the bigger the hill is (activation energy), the slower the reaction is to complete?
 
Last edited:
He told you the Arrhenius equation K= A ^Ea/RT .This relates Ea to K through an exponential function. They aren't inversely related because they aren't proportional but for simplicity's sake you can take of it as inversely proportional where if Ea gets bigger then K gets smaller. Just something you need to know.

However conceptually you can compare Ea better to the rate than the rate constant. Because if there is a bigger activation energy then the rate will decrease because it will take longer to overcome the activation energy.